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Your source for carbon and sulfur analysis



UIC, Inc.Adaptation of the Modified Monier-Williams Method


As in the modified Monier-Williams method, samples are treated with acid and heated to release SO2. A nitrogen carrier gas sweeps the SO2 through a reflux condenser and into the S Coulometer cell. The S Coulometer automatically titrates the SO2 and digitally displays the amount.


  1. Assemble and prepare the components for operation as described in the instruction manuals.
  2. Determine the blank and run a standard to confirm proper operation of the system.
  3. Charge the sample tube with a known weight of sample and attach the tube to the apparatus. Sample size should be selected to contain 1-3mg of SO2.

    Note: Solid and viscous liquid samples may either be weighed out directly into the sample tubes or weighed out into porcelain, platinum, alumina or similar sample containers and then placed in the tube. Water and liquid samples handles with a syringe can be directly injected through the septum at the top of the apparatus.

  4. Move the sample tube into position over the heater, pump acid into the reaction tube, and reset the coulometer.

    Note: When injecting samples, a sample tube with a stopcock can be used. This eliminates the need to open the system between sample runs.

  5. 5. When all of the SO2 has been evolved and titrated, the CM5017S automatically detects the endpoint, ends the analysis and prints the result to the printer and/or diskette.

(*) – Endpoint determination and result calculations are performed automatically based on user selectable settings entered into the CM5017S Coulometer.


When samples contain over 1 mg SO2, the coulometer measurement repeatability is +/-0.15%. Reproducibility is typically +/-0.5% at 1000 ppm. When sample availability or volume limits the amount of SO2 evolved to small amounts, the precision is generally better than 1 ug SO2. Sample stability can limit both the accuracy and precision of the test.

Analysis times are typically 10 to 15 minutes. Some samples react very slowly, thus extending the analysis time.

A major advantage of the S Coulometer is the analysis completion can be observed. Low results due to incomplete reactions and wasted time can thus be avoided. Other advantages include the easy operation of the system and option modification for using different acids, carrier gases or scrubbers for different applications.


Table I

Comparison of Total Sulfites in Dried Fruit (% SO2)

SampleMonier – WilliamCoulometricp-rosanailine
White Raisins0.397%0.007%0.370%0.008%0.366%0.014%

Table II

Total Sulfites in Beer (mg SO2/L)

Beer A1.090.081.460.03
Beer B4.950.045.860.09
Beer C1.920.033.760.11
Beer D2.760.053.720.42

Table III

Total Sulfites in Wine (mg SO2/L)

SampleCoulometricMonier – Williams
Red Wine822894
White Wine13221386
Red Wine Vinegar782796