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UIC Inc. Coulometer Systems – Frequently Asked Questions

UIC Inc. Coulometer Systems - Frequently Asked Questions

System Specifications & Performance

Our carbon analyzer coulometer systems measure less than 2 μg of carbon.

  • Accuracy: ±1.25% of the true value

  • Precision (RSD): ±0.2%

100 mg of carbon (equivalent to 367 mg of CO₂ or 500 mg of CO₃) per 100 ml of solution.

Sample Types & Measurement Capabilities

Yes, UIC Inc. offers systems that can measure both solid and liquid samples.

Yes, but larger sample weights may be required for extremely low concentrations of the desired product. Higher concentrated solutions typically require approximately 2,000 to 5,000 μg, while the furnace units can handle samples weighing from approximately 0.1g to 5g.

Yes, we can test your carbon samples in our lab.

Measurement Process & Methods

Samples are measured using coulometry with different front-end units:

  • TOC (Total Organic Carbon): Coulometer and a furnace at approximately 600°C

  • TC (Total Carbon): Coulometer and a furnace at approximately 1000°C

  • TIC (Total Inorganic Carbon): coulometer and an acidification unit

The coulometer electrochemically titrates the absorbed carbon until the spectrophotometric endpoint is achieved, which is a factory-set endpoint of 29.5%T.

Calibration & Standards

Calibration is not required because the coulometers are based on Faraday’s fundamental electrochemical laws. However, it is recommended to run standards sporadically to ensure everything works properly.

Electrode Maintenance & Issues

The silver is consumed in the chemical reaction during normal operation. This is expected behavior.

This is normal and consists of Silver Sulfide (AgS).

This is normal and consists of Silver Iodide (AgI).

Sample Considerations

Consider whether any of the desired sample components will volatilize at temperatures slightly higher than 100°C. If so, a moisture-measuring device may be required to obtain accurate measurements on a wet sample basis.

  • Sample size requirements depend on concentration levels

  • Wet samples require constant weight measurements

  • Larger sample weights improve results for low-concentration samples

  • Consider volatilization potential when drying samples

Application Information

When requesting a quote or system information, please provide:

  • Description of your application and what you need to measure

  • Whether you work with liquid and/or solid samples

  • Average sample size (mg, ml, cm², etc.)

  • Average concentration ranges (mg/g, mg/kg, mg/L, etc.)

  • Expected detection limit requirements

  • Any special sampling, handling, or working requirements

Specialized Applications

UIC Inc. offers systems specifically designed for:

  • Oceanographic applications (water and sediment samples)

  • Simultaneous measurement of carbon and sulfur

  • Total, organic, and/or inorganic carbon measurements

  • Total, organic, and/or inorganic sulfur measurements

  • Simultaneous inorganic carbon and sulfur measurements

Note: All ranges and specifications can be adjusted for specific client applications and requirements.